Diels-Alder chemistry of siloles and their transformation into cyclohex-2-ene-1,4-cis-diols.
نویسندگان
چکیده
The synthesis of siloles with substitution patterns that are continuative toward natural product synthesis are described. Their reactivity in Diels-Alder chemistry was explored through thermal, Lewis acid, and high-pressure reactions. Furthermore, bicyclic adducts were oxidatively cleaved to reveal a highly functionalized cyclohexene core.
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عنوان ژورنال:
- Organic letters
دوره 12 16 شماره
صفحات -
تاریخ انتشار 2010